肉桂醛及其氯代物与多元醇缩合物的合成及其凝胶性能研究  

Synthesis of Organic Glators Based on Acetals Condensed from Cinnamic Aldehyde With Polyols and Studies of the Gel Properties

作　　者：林惠文[1] 邓鹏飞[1] 李天略[1] 

机构地区：[1]海南师范大学化学化工学院,海南海口571158

出　　处：《海南师范大学学报（自然科学版）》2010年第2期181-184,共4页Journal of Hainan Normal University（Natural Science）

基　　金：海南省自然科学基金项目(20605);海南师范大学博士科研启动基金项目(103311)

摘　　要：用肉桂醛、对氯肉桂醛、邻氯肉桂醛为原料,采用环己烷-甲醇混合溶剂体系,以对甲苯磺酸为催化剂,分别与木糖醇、山梨醇反应,合成5种多元醇缩醛类凝胶因子,用核磁共振谱氢做了结构鉴定,测试了它们的凝胶性能、最低凝胶浓度和凝胶解缔温度等.Five low-molecular mass organic glators were synthesized by cinnamic aldehyde or chlorcinnamic aldehyde respectively with xylitol, sorbitol, mannitol, using p-toluensesulfonic acid as catalyst and removing water by azeotropic distillation with cyclohexane. Their structures were confirmed by 1HNMR. The performance of the gels were tested by using 22 organic solvents. The minimum concentrations （w%） and Sol-Gel Transitions temperature of products were measured.

关 键 词：凝胶因子 肉桂醛 多元醇 

分 类 号：O641[理学—物理化学]