Ligand selection for complex-leaching valuable metals in hydrometallurgy  

作　　者：杨天足 窦爱春 雷存茂 任晋 刘珍珍 

机构地区：[1]School of Metallurgical Science and Engineering,Central South University

出　　处：《Transactions of Nonferrous Metals Society of China》2010年第6期1148-1153,共6页中国有色金属学报（英文版）

基　　金：Project(2007CB613604) supported by the National Basic Research Program of China

摘　　要：A two-stage ligand selection method composed of a primary selection and a critical selection,for complex-leaching valuable metals was presented.At the primary selection stage,three conditions were discussed under a supposed ideal state by mathematical derivation.Generally,ligands selected under condition Ⅰwere easier for complex-leaching valuable metals than that under conditionⅡ,however,under conditionⅢ,ligands selected were hard to complex-leaching the valuable metals.Ligands that were out of these three conditions could be disposed directly.In critical selection,ligands selected in primary selection can be finalized.Case applications were provided for verifying the method.The application indicated that iminodiacetate(Ida2-)can be used as a complex agent for complex-leaching smithsonite(ZnCO3);the leaching condition should be controlled with pH 8-11;the relative error of the minimum consumption of Ida2-between the predicted and the calculated results is 5.3%.The results indicate that the theoretical derivations in the ideal state are reliable,and the method for ligand selection is practical and operable.A two-stage ligand selection method composed of a primary selection and a critical selection,for complex-leaching valuable metals was presented.At the primary selection stage,three conditions were discussed under a supposed ideal state by mathematical derivation.Generally,ligands selected under condition Ⅰwere easier for complex-leaching valuable metals than that under conditionⅡ,however,under conditionⅢ,ligands selected were hard to complex-leaching the valuable metals.Ligands that were out of these three conditions could be disposed directly.In critical selection,ligands selected in primary selection can be finalized.Case applications were provided for verifying the method.The application indicated that iminodiacetate（Ida2-）can be used as a complex agent for complex-leaching smithsonite（ZnCO3）; the leaching condition should be controlled with pH 8-11; the relative error of the minimum consumption of Ida2-between the predicted and the calculated results is 5.3%.The results indicate that the theoretical derivations in the ideal state are reliable,and the method for ligand selection is practical and operable.

关 键 词：ligand selection complex-leaching SMITHSONITE HYDROMETALLURGY 

分 类 号：TF111.3[冶金工程—冶金物理化学]