咔唑类化合物研究新进展  

New Progress of Researches in Carbazole Compounds

作　　者：张飞飞[1] 周成合[1] 颜建平[1] 

机构地区：[1]西南大学化学化工学院,重庆400715

出　　处：《有机化学》2010年第6期783-796,共14页Chinese Journal of Organic Chemistry

基　　金：西南大学人才引进基金(No.SWUB2006018);西南大学高新技术培育基金(No.XSGX0602);重庆市自然科学基金(No.CSTC2007BB5369)资助项目

摘　　要：咔唑及其衍生物是一类重要的含氮芳杂环化合物,分子内含有较大的共轭体系和强的分子内电子转移,这种特殊的刚性稠环结构使咔唑类化合物表现出许多独特的性能及生物活性,在光电材料、染料、医药、超分子识别等多领域具有潜在的广泛应用.更为重要的是咔唑类化合物易于进行结构修饰,在咔唑环上可方便地引入各种功能基,咔唑衍生物的合成及其开拓咔唑类化合物潜在的新用途,成为近些年来十分活跃的研究领域,且发展迅速.结合自己的工作,参考国内外文献,全面综述了咔唑类化合物在有机电致发光材料、光折变材料、太阳能电池材料、染料、医药和超分子识别等领域的研究与开发新进展,并对其发展趋势作了展望.Carbazole and its derivatives are an important type of nitrogen-containing aromatic heterocyclic compounds,possess desirable electronic and charge-transport properties,as well as large π-conjugated system with rigid fused rings.These special structures of carbazole compounds endow their distinct various functions,properties and biological activities,as well as wide potential application in photoelectrical materials,dyes,medicinal agents,supramolecular recognition and so on.More importantly,the carbazole compounds are easily modified and various functional groups could be conveniently introduced into the carbazole ring.The syntheses of carbazole derivatives and their potential applications were extensively investigated and have been become highly active highlight in recent years,and the progress is quite rapid.Combining with our researches and referring other works from literatures,this paper systematically reviews the recent advance in the research and development of carbazoles in organic electro-luminescence materials,organic photorefractive materials,solar cells,dyes,medicinal chemistry,supramolecular recognition and so on.The perspectives of the foreseeable future are also presented.

关 键 词：咔唑 电致发光 染料 抗癌 超分子识别 

分 类 号：O626.2[理学—有机化学]