铜(Ⅱ)与2-吡啶酸、4,4′-联吡啶配合物的合成、结构和电化学性质(英文)  

Synthesis,Crystal Structure and Cyclic Voltametric Property of Cu(Ⅱ) Complex with 4,4'-Bipy and α-Pyridine Carboxylate

作　　者：吴刚[1] 王小锋 鲜华 郭学林[1] 

机构地区：[1]滁州学院化学和生命科学系,滁州239012 [2]晓庄学院生物化工与化境工程学院,南京211171

出　　处：《无机化学学报》2010年第7期1315-1318,共4页Chinese Journal of Inorganic Chemistry

基　　金：安徽省高校自然科学基金资助(No.KJ2009B104);安徽省应用化学重点建设学科基金资助(No.200802187C)

摘　　要：The complex [Cu(bipy)(pc)(H2O)(ClO4)]·H2O(1)(bipy:4,4'-bipyridine;Hpc:α-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It crysrallizes in the Monoclinic space group P21/n.The crystal structure reveals that Cu(Ⅱ) centre adopts a pseudo octahedral geometry.Ligand 4,4'-bipyridine as a bridge coordinates to two different Cu(Ⅱ) center to form a onedimensional zigzag chain.One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer.Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure.The cyclic voltametric behavior of complex 1 is also investigated.The complex [Cu（bipy）（pc）（H2O）（ClO4）]·H2O（1）（bipy：4,4＇-bipyridine;Hpc：α-pyridine carboxylic acid） has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It crysrallizes in the Monoclinic space group P21/n.The crystal structure reveals that Cu（Ⅱ） centre adopts a pseudo octahedral geometry.Ligand 4,4＇-bipyridine as a bridge coordinates to two different Cu（Ⅱ） center to form a onedimensional zigzag chain.One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer.Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure.The cyclic voltametric behavior of complex 1 is also investigated.

关 键 词：Cu髤配合物 4 4′-联吡啶 晶体结构 循环伏安 

分 类 号：O614.121[理学—无机化学]