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作 者:Xu Xin Zhao Tianbo Qi Jian Miao Ce (The Institute for Chemical Physics,Beijing Institute of Technology,Beijing 100081)
出 处:《China Petroleum Processing & Petrochemical Technology》2010年第2期22-28,共7页中国炼油与石油化工(英文版)
基 金:Financial supports from the National Natural Science Foundation of China(No.20973022)
摘 要:Micrometer-scale macroporous aluminosilicate catalyst was prepared via the sol-gel process. Results of catalytic cracking of 1, 3, 5-triisopropylbenzene showed that the synthesized aluminosilicate catalyst exhibited much higher activity than traditional ZSM-5 zeolite under the same condition. It is worth mentioning that the polymer product selectivity of aluminosilicate was much lower than that of ZSM-5, which might be useful for implementing the catalytic cracking process. The unique structure of macroporous aluminosilicate with interconnected-macropores and continuous skeletons was believed to be responsible for its excellent catalytic activity and low polymer product selectivity. Detailed discussion on the reaction pathway was also conducted.
关 键 词:ALUMINOSILICATE MACROPOROUS 1 3 5-triisopropylbenzene reaction pathway
分 类 号:TE624.9[石油与天然气工程—油气加工工程]
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