含(4-磷酸)苯侧基聚芳醚砜的合成及杂化  

Synthesis and Hybrid of a (4-Phosphonic acid) phenylated Poly(arylene ether sulfone)

作　　者：刘佰军[1] 李雪峰[1] 郭梅梅[1] 刘畅[1] 李龙[1] 姜振华[1] 

机构地区：[1]吉林大学麦克德尔米德实验室,长春130012

出　　处：《高等学校化学学报》2010年第6期1081-1083,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:50973040);吉林省科技发展计划(批准号:20090322)资助

摘　　要：A bromine-containing poly(arylene ether sulfone) was synthesized from a(4-bromo)phenylhydroquinone monomer.A phosphonated derivative was prepared based on above brominated polymer using palladium-catalyst.Aimed at improving the properties for fuel cell applications,a composite membrane was obtained by incorporating sulfonic acid-functionalized polysilsesquioxane into the phosphonated polymer through a sol-gel processing.Both phosphonated membrane and its hybrid membranes show good thermal and dimensio-nal stability.The hybrid membrane has low methanol permeability of 1.07×10-7 cm2/s and proton conducti-vity of 0.06 S/cm at 80 ℃.A bromine-containing poly（arylene ether sulfone） was synthesized from a（4-bromo）phenylhydroquinone monomer.A phosphonated derivative was prepared based on above brominated polymer using palladium-catalyst.Aimed at improving the properties for fuel cell applications,a composite membrane was obtained by incorporating sulfonic acid-functionalized polysilsesquioxane into the phosphonated polymer through a sol-gel processing.Both phosphonated membrane and its hybrid membranes show good thermal and dimensio-nal stability.The hybrid membrane has low methanol permeability of 1.07×10-7 cm2/s and proton conducti-vity of 0.06 S/cm at 80 ℃.

关 键 词：质子交换膜 燃料电池 聚芳醚砜 杂化 

分 类 号：O631[理学—高分子化学]