合成甲醇铜系催化剂的研究  

Study on Copper System Catalysts of Methanol Synthesis

作　　者：韩志山[1,2] 高丽萍[1,2] 吴静[1,2] 蒋春英[1,2] 殷恒波[1,2] 

机构地区：[1]沈阳化工研究院 [2]沈阳化工学院

出　　处：《辽宁化工》1999年第1期43-44,共2页Liaoning Chemical Industry

摘　　要：研究了低压合成甲醇中Ｃｕ系催化剂共沉淀制备方法，沉淀剂对甲醇合成性能的影响，在空速１２０００ｈ－１，压力５０ＭＰａ下，Ｃｕ∶Ｚｎ∶Ｃｒ（４５∶５０∶５）催化剂的时空收率可达２．４６ｍｌ甲醇／ｍｌ催化剂·ｈ。Ｃｏ的加入有利于提高共沉淀法制备的Ｃｕ、Ｚｎ、Ａｌ及Ｃｕ、Ｚｎ、Ｃｒ系催化剂的耐硫性能。The copper system catalystswere prepared by coprecipitation method. The influence of the copper content,the feed method and the precipitants on the activity of the catalysts was studied.The sulphidation-resistance of the catalysts was discussed. The experimental results showed that the high copper content increases the activity of the catalysts. It is in favor of the dispersion of active component that the precipitant and active components are fed at the same time. As a recipitant,NH 4HCO 3 can raise the activity of the catalysts. Besides,it can not pollute the catalysts. The addition of Co increases the sulphidation-resistance of the catalysts.

关 键 词：合成甲醇 铜 催化剂 共沉淀 甲醇 

分 类 号：TQ223.121[化学工程—有机化工] TQ426.8