可溶性聚对苯乙炔衍生物的合成与表征  

Synthesis and Characterization of Soluble Poly(p-phenylene Vinylene) Derivatives

作　　者：张小舟[1,2] 蹇锡高[2] 卢新坤[1] 

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161006 [2]大连理工大学化工学院,辽宁大连116012

出　　处：《河北师范大学学报（自然科学版）》2010年第4期443-447,共5页Journal of Hebei Normal University：Natural Science

基　　金：齐齐哈尔科学技术计划项目(GYGG-0810-2)

摘　　要：用脱氯化氢法合成了4种聚对苯乙炔的衍生物.通过实验分析了催化剂和原料对中间产物以及聚合物产率的影响.通过红外、核磁等方法表征了聚合物的结构,通过热失重曲线表征了聚合物的热稳定性,从苯环上的烷氧基取代的侧链长度方面对聚合物热稳定性、溶解性和分子量进行了研究.Four kinds of PPV derivatives with symmetrical and asymmetrical alkoxyl substitutes are prepared by dehydrochlorination process with p-methoxylphenol and p-diphenol as raw materials.They are poly（2-methoxy-5butyloxy-1,4-phenylenevinylene）,poly（2-methoxy-5-octyloxy-1,4-phenylenevinylene）,poly（2me-thoxy-5-（iso-octyloxy）-1,4-phenylenevinylene）,poly（2-methoxy-5-dodecyloxy-1,4-phenylenevinylene）.In comparison with PPV,the four kinds of PPV derivatives can resolve in some organic solvent.The influences of synthesis route and reaction conditions are investigated roughly.The structure of the four kinds of PPV derivatives are characterized with FTIR.The thermal stability and thermo performance are obtained from TG curves.The molecular weight is measured by GPC.

关 键 词：聚对苯乙炔 合成 发光聚合物 热稳定性 

分 类 号：O632.17[理学—高分子化学]