新型吡啶双羧酸席夫碱配体锌配合物的合成、晶体结构及荧光性质(英文)  

Synthesis,Crystal Structure and Photoluminescent Property of a Zinc(Ⅱ) Complex Based on Novel Pyridyl-dicarboxylate Schiff-Base Ligand

作　　者：王彦[1,2] 王涛[1] 刘光祥[1] 陈友存[1] 

机构地区：[1]安庆师范学院化学化工学院,安徽省功能配合物重点实验室,安庆246011 [2]南京大学配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2010年第8期1467-1471,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20901004,20971004,20771006)资助项目

摘　　要：A novel pyridyl-dicarboxylate Schiff-base ligand (5-((pyridin-3-ylmethyl)amino)isophthalic acid,H2L) and its Zinc(Ⅱ) complex,namely,ZnL (1),were synthesized. The ligand was characterized by NMR analysis. The X-ray crystallographic analysis on complex 1 shows that 1 crystallizes in homoclinic,space group P21/c with a= 0.753 83(10) nm,b=1.040 52(14) nm,c=1.734 67(19) nm,β=112.123(5)°,V=1.260 5(3) nm3,Z=4,Dc=1.769 g· cm-3,F(000)=680,μ=1.966 mm-1,the final R=0.030 8,wR=0.085 6. In complex 1,the coordination environment of Zn(Ⅱ) is distorted tetragonal-pyramid with N1O4 set. The 2D 4,4-topological sheets in 1 packed along a axis to form its 3D framework,which was stabilized by the π…π interactions between the adjacent aromatic rings on the neighbouring sheets. The photoluminescent property of 1 was also investigated.A novel pyridyl-dicarboxylate Schiff-base ligand （5-（（pyridin-3-ylmethyl）amino）isophthalic acid,H2L） and its Zinc（Ⅱ） complex,namely,ZnL （1）,were synthesized. The ligand was characterized by NMR analysis. The X-ray crystallographic analysis on complex 1 shows that 1 crystallizes in homoclinic,space group P21/c with a= 0.753 83（10） nm,b=1.040 52（14） nm,c=1.734 67（19） nm,β=112.123（5）°,V=1.260 5（3） nm3,Z=4,Dc=1.769 g· cm-3,F（000）=680,μ=1.966 mm-1,the final R=0.030 8,wR=0.085 6. In complex 1,the coordination environment of Zn（Ⅱ） is distorted tetragonal-pyramid with N1O4 set. The 2D 4,4-topological sheets in 1 packed along a axis to form its 3D framework,which was stabilized by the π…π interactions between the adjacent aromatic rings on the neighbouring sheets. The photoluminescent property of 1 was also investigated. CCDC：769437

关 键 词：晶体结构 锌配合物 席夫碱 π…π相互作用 荧光 

分 类 号：O614.242[理学—无机化学]