HRGC/ECNI-LRMS测定大辽河入海口表层沉积物中短链氯化石蜡  

Analysis of Short-chain Chlorinated Paraffins in Sediment Samples from the Mouth of the Daliao River by HRGC/ECNI-LRMS

作　　者：高媛[1] 王成[1] 张海军[1] 邹黎黎[1] 田玉增[1] 陈吉平[1] 

机构地区：[1]中国科学院大连化学物理研究所,大连116023

出　　处：《环境科学》2010年第8期1904-1908,共5页Environmental Science

基　　金：国家重点基础研究发展规划(973)项目(2009CB421602)

摘　　要：联合使用酸化硅胶层析柱和中性氧化铝层析柱净化处理沉积物样品中的短链氯化石蜡(SCCPs),并对净化条件进行优化,在此基础上,建立了沉积物中SCCPs的高分辨气相色谱/电子捕获负离子化-低分辨质谱(HRGC/ECNI-LRMS)分析方法.应用该方法分析研究了大辽河入海口表层沉积物中SCCPs的含量和各同系物组分的分布模式.结果表明,大辽河入海口表层沉积物中SCCPs以C10-SCCPs和C11-SCCPs为主,含量在64.9～407.0 ng/g之间,且随着向海洋方向延伸,SCCPs含量呈现下降趋势.An analytical method for quantifying short-chain chlorinated paraffins（SCCPs） by high-resolution gas chromatography/electron capture negative ion low-resolution mass spectrometry（HRGC/ECNI-LRMS） was presented.The cleanup procedure with an acid silica gel column and activated neutral alumina column was optimized to remove the interferences.As illustration of the application of the method to environmental samples,it is found that lower chlorinated C10 and C11 compounds were the main SCCPs compounds in six sediment samples from the mouth of the Daliao River.The concentrations of SCCPs in sediments were determined to be in the range of 64.9-407.0 ng/g and showed a decreasing tendency from the shore to the remote location.

关 键 词：短链氯化石蜡 沉积物 分析方法 高分辨气相色谱/电子捕获负离子化-低分辨质谱 

分 类 号：X832[环境科学与工程—环境工程]