纺锤状CuO纳米晶制备及催化性能的研究  

Synthesis and Catalytic Property of Spindle-like CuO Nanocrystals

作　　者：邹菁[1,2] 黄蕾[1] 袁军倩[1] 江吉周[1] 万其进[1,2] 陈金芳[1,2] 

机构地区：[1]武汉工程大学化工与制药学院,武汉430073 [2]湖北省新型反应器与绿色化学工艺重点实验室,武汉430073

出　　处：《武汉理工大学学报》2010年第13期26-29,33,共5页Journal of Wuhan University of Technology

基　　金：湖北省自然科学基金(2009CDB078)

摘　　要：采用水热法,以醋酸铜为铜源,氢氧化钠为沉淀剂,聚丙烯酸为软模板,通过调控不同的合成参数,制备了纺锤状CuO纳米晶。同时重点探讨了聚合物种类和碱的浓度对CuO纳米晶产物形貌的影响。采用HRTEM、SEM、XRD、EDS、Raman等对产物的形貌、结构、成分、光学性质进行了表征。结果表明产物是纯的单斜CuO纳米单晶。并考察了纺锤状CuO纳米晶对甲基橙在H2O2协同作用下超声催化降解作用。Spindle-like CuO nanocrystals were prepared with Cu（ac）2 as copper source,NaOH as precipitator and polypropylene as a soft template under controlling different synthesis parameters by a hydrothermal method.The effect of the kind of polymer and alkaline concentration on the morphologies of products were concentrated on discussing.The morphology,structure,component and optical property of CuO nanocrystals obtained were characterized by HRTEM,SEM,XRD,EDS,Raman respectively.The results showed that products were pure monoclinic CuO nanocrystals.At the same time,the catalysis degeneration of methyl orange solution under spindle-shaped CuO nanocrystalline in H2O2 synergistic effects by ultrasonic were also visited.

关 键 词：氧化铜 纳米晶 水热法 催化降解 

分 类 号：O782.2[理学—晶体学]