二茂铁基亮氨酸锌配合物的晶体结构与性质  

Crystal and properties of a zinc ferrocenoyl leucine complex

作　　者：徐虹[1] 张宇虹[1] 常玉珊[1] 谢少沛[1] 侯红卫[1] 

机构地区：[1]郑州大学化学系,河南郑州450052

出　　处：《化学研究与应用》2010年第8期995-998,共4页Chemical Research and Application

基　　金：国家自然科学基金(J0830412)项目资助;河南省教育厅自然科学研究计划项目(2010A150025)资助

摘　　要：A new chiral mono-complex(S)-[Zn(FcCH2NHCH(CH2CH(CH3)2)COO)2·H2O]·3H2O has been synthesized by the reaction of(S)-FcCH2NHCH(CH2CH(CH3)2)COONa and ZnAc2.X-ray diffraction technique reveals that the central Zn2+ ion coordinates with two(S)-FcCH2NHCH(CH2CH(CH3)2)COO-and one water molecule.The crystal belongs triclinic with space group P1.The cell parameters are:a=11.1883(4) ;b=11.1934(4) ;c=30.6717(15) ;α=97.6160(10)°,β=97.6120(10)°,γ=90.157(11)°.The electrochemical properties and fluorescence properties of the title complex and the pure ligand are determined.A new chiral mono-complex（S）-[Zn（FcCH2NHCH（CH2CH（CH3）2）COO）2·H2O]·3H2O has been synthesized by the reaction of（S）-FcCH2NHCH（CH2CH（CH3）2）COONa and ZnAc2.X-ray diffraction technique reveals that the central Zn^2＋ ion coordinates with two（S）-FcCH2NHCH（CH2CH（CH3）2）COO-and one water molecule.The crystal belongs triclinic with space group P1.The cell parameters are：a=11.1883（4） ;b=11.1934（4） ;c=30.6717（15） ;α=97.6160（10）°,β=97.6120（10）°,γ=90.157（11）°.The electrochemical properties and fluorescence properties of the title complex and the pure ligand are determined.

关 键 词：配合物 二茂铁甲基亮氨酸钠 晶体结构 电化学性质 荧光性质 

分 类 号：O635.2[理学—高分子化学]