Spheripol聚丙烯工艺的环管反应器模拟  

MODELING OF LOOP REACTOR FOR POLYPROPYLENE SPHERIPOL TECHNOLOGY

作　　者：施德磐[1] 李晓军[2] 苏培林[1] 郑祖伟[1] 罗正鸿[1] 

机构地区：[1]厦门大学化学化工学院化学工程与生物工程系,福建厦门361005 [2]中国石油兰州石化公司聚烯烃事业部,甘肃兰州730060

出　　处：《石油学报（石油加工）》2010年第4期582-587,共6页Acta Petrolei Sinica(Petroleum Processing Section)

基　　金：中国石油天然气股份有限公司兰州石油化工研究中心项目(2008015)资助

摘　　要：在Aspen Polymers Plus软件平台上模拟Spheripol聚丙烯工艺中核心液相环管反应器,采用了等效的全混流反应器模型和组合式环管反应器模型,结合工厂现场采集的数据,拟合了丙烯聚合反应动力学模型,并将该模型用于2种环管反应器模拟方法的比较。采用组合式环管反应器模型考察了丙烯聚合反应循环比对反应器撤热、聚丙烯产量和相对分子质量分布、反应器内氢气浓度分布的影响。结果表明,在高循环比操作条件下和误差允许范围内,环管反应器可以等效为一个全混流反应器。当控制环管反应器夹套冷却水出口温度不变时,过低的循环比使得反应器内的温度分布不均匀,而过高的循环比则使环管反应器的撤热能力下降;当循环比增加时,环管反应器内的温度和组分浓度梯度减小,停留时间分布均匀,趋于全混流状态,催化剂活性得到充分发挥,聚丙烯产量也相应增加。Both the continuous stirred tank reactor model and the combined tubular loop reactor model were set up to simulate the steady-state performance of the industrial tubular loop reactor of Spheripol technology of propylene polymerization based on the Aspen Polymers Plus software.A comprehensive catalyzed polymerization kinetic model was verified by using plant data,and was employed to analyze the operational performance of the two models.It was observed that in high recycle ratio for propylene polymerization,the tubular loop reactor could be simulated,to a certain error degree,by a continuous stirred reactor.In addition,the effects of recycle ratio on the performance of the loop reactor could also be obtained via the combined model.The simulated results showed that the low recycle ratio made the temperature change along the tubular loop reactor in a large range under the constant coolant outlet temperature,while the high recycle ratio made the reaction temperature uniform in the tubular loop reactor,but the capacity of heat evacuation reduced.On the other hand,with the increase of recycle ratio,the concentration gradients of reaction components were lowered,and the polypropylene production was enlarged,approaching to the performance of the continuous stirred reactor.

关 键 词：聚丙烯 环管反应器 稳态模拟 Polymers Plus 

分 类 号：O643.32[理学—物理化学]