金刚烷——新一代化工原料  

Adamantane:a New Generation of Chemical Raw Material

作　　者：王永杰[1] 

机构地区：[1]沈阳工业大学(辽阳校区)石油化工学院,辽阳111003

出　　处：《价值工程》2010年第25期128-129,共2页Value Engineering

基　　金：2010年辽宁省教育厅科研项目:<金刚烷-新一代化工原料>(L2010409)

摘　　要：简要介绍了金刚烷的结构、性质、制备方法及应用。造成金刚烷收率低的原因:没有掌握提高金刚烷收率的关键,即发挥助催化剂的协同作用,有利于生成金刚烷的主反应,未找到有效抑制副反应的办法。对三氯化铝法和出光法的改进,特别是提高金刚烷的收率、探索合成金刚烷的其它新催化工艺仍是今后研究工作的重点,也是金刚烷化学发展的难点和热点。并预言本世纪将出现一门新的分支学科——金刚烷化学。This paper briefly introduced the structure, properties, method of preparation and application of adamantane. The reason of adamantane of lower yield is without a grasp of the key to improve the yield of adamantane, namely, playing the catalyst reaction of the synergy is helpful to the generation of adamantane, but having not found effective methods for suppression of adverse reaction. It is still the research focus to improve Alcl3 method and glaring method, especially to improve the yield of adamantane and explore the other new catalytic processes for combining adamantane, and it is also the different and hot point of adamantane＇ chemical development. And this paper predicts that there will be a new sub-discipline： Adamantane Chemistry.

关 键 词：金刚烷 性质 制备 应用 

分 类 号：O6[理学—化学]