二(五氯苯氧基)二茂钛配合物合成方法研究——有机相、水相及两相法  

Synthesis of biscyclopentadienyl titanium dipentachlorophenoxy coordination compound Synthesis method in organic, aqueous and two phase

作　　者：高子伟[1] 张尊听[1] 高玲香[1] 

机构地区：[1]陕西师范大学化学系

出　　处：《陕西师大学报（自然科学版）》1999年第2期65-66,共2页Journal of Shaanxi Normal University(Natural Science Edition)

摘　　要：采用［Ｃｐ２Ｔｉ（ａｃａｃ）］＋，分别由水相法和两相法合成了二（五氯苯氧基）二茂钛配合物，并对有机相合成法进行了改进，其产率分别为７３％，７０％，４６％．实验表明，两相法具有操作简便、条件温和、反应时间短、现象明显等优点；配合物用元素分析。An organic titanium coordination compound,Cp 2(OC 6Cl 5) 2,is prepared from aqueous phase and organic aqueous phase respectively by using dicyclopentadienyl dichlorotitanium(Ⅳ),acetyacetone and pentachlorophenol as starting reagents. The traditional method for the preparation of the coordination compound in organic medium is improved. The yields of the three method are 73%, 70% and 46%, respectively. The coordination compound is characterized by their elemental analysis, IR and 1H NMR spectra.

关 键 词：二茂钛配合物 合成 水相法 有机相法 五氯苯氧基 

分 类 号：O627.43[理学—有机化学] O614.411[理学—化学]