双(1-氮杂环基)二硫代氨基甲酸铜(Ⅱ)、锌(Ⅱ)配合物的合成及结构表征  

SYNTHESIS AND CHARACTERIZATION OF COPPER(Ⅱ), ZINC(Ⅱ) COMPLEXES SUPPORTED BY BIS(1 HETEROCYCLO )DITHIOCARBAMATO LIGANDS

作　　者：郭胜利[1,2] 殷元骐[1,2] 

机构地区：[1]四川大学化学系 [2]中国科学院兰州化学物理研究所

出　　处：《四川大学学报（自然科学版）》1999年第3期562-565,共4页Journal of Sichuan University(Natural Science Edition)

摘　　要：Ｚｎ（ＩｍＨ）２（Ｃｌ）２（１ａ），Ｃｕ（ＩｍＨ）４（Ｃｌ）２（１ｂ）分别与吡咯烷、吗啉、４甲基哌嗪的１位二硫代氨基甲酸钾反应，得到四个相应的配合物．产物经ＩＲ、１ＨＮＭＲ及元素分析等方法表征，表明１ａ、１ｂ中的配体咪唑和氯原子全部被配位能力更强的（１氮杂环基）二硫代氨基甲酸根所取代．Four complexes were synthesized by the reaction of Zn(ImH) 2(Cl) 2(1a),Cu(ImH) 4(Cl) 2(1b) with potassium dithiocarbamate RCS 2K(R=pyrrolidinyl,morpholino,4 methylpiperazinyl).These complexes were characterized by IR, 1HNMR and elemental analysis.The results showed that ligands of imidazole and chloro atoms in 1a,1b were completely replaced by dithiocarbamato ligands with strong coordinative ability.The complex bis[(4 methylpiperazinyl) dithiocarbamato] copper(Ⅱ) was further characterized by X ray crystal structure determination.

关 键 词：二硫代氨基甲酸 铜 锌 配合物 合成 晶体结构 

分 类 号：O614.121[理学—无机化学] O614.241[理学—化学]