催化加氢法合成芳磺酸氨基化合物  

The Synthesis of Aminoarylsulfonic Acid by Catalytic Hydrogenation

作　　者：孟明扬[1] 王玉灿[1] 杨文东[1] 马瑛[1] 高嘉新[1] 刘东[1] 

机构地区：[1]沈阳化工研究院有限公司,沈阳110021

出　　处：《染料与染色》2010年第4期43-45,共3页Dyestuffs and Coloration

摘　　要：本文阐述了w-2型兰尼镍催化剂在芳磺酸硝基化合物催化加氢还原制备芳磺酸氨基化合物中的应用。以间硝基苯磺酸的催化加氢反应为例进行实验,实验结果表明,在反应温度80～100℃,反应压力1MPa,反应时间3小时的条件下,间氨基苯磺酸产品的含量为99%,收率可达99%以上,催化剂可以连续循环使用20次。The application of W-2 Raney Ni in the catalytic hydrogenation of nitroarylsulfonic acid to prepare aminoarylsulfonic acid was described.Based on the experiments of the catalytic hydrogenation of m-nitrobenzenesulfonic acid,the results showed that under the conditions of reaction temperature 80~100℃,pressure 1MPa and reaction time 3 hours,the content of m-aminoarylsulfonic acid achieved 99%,the yield was up to 99%,and the catalyst could be continuously reused for 20 times.

关 键 词：催化剂 加氢 间硝基苯磺酸 间氨基苯磺酸 

分 类 号：TQ612[化学工程—精细化工]