Cyclopalladated ferrocenylimines as efficient catalysts for homogeneous catalysis:A brief introduction to our preliminary achievements  

作　　者：WU YangJie YANG Fan ZHANG JinLi CUI XiuLing GONG JunFang SONG MaoPing LI TieSheng 

机构地区：[1]Department of Chemistry, Key Laboratory of Chemical Biology and Organic Chemistry of Henan Province, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, China

出　　处：《Chinese Science Bulletin》2010年第25期2784-2793,共10页

基　　金：supported by the National Natural Science Foundation of China (20772114);the Innovation Fund for Outstanding Scholar of Henan Province (0621001100)

摘　　要：Cyclopalladated ferrocenylimines as a novel kind of highly efficient palladium catalyst precursors, which are air-stable and easy to handle, have been successfully applied in a wide variety of catalytic reactions ranging from classical reactions, such as Heck, Suzuki, Sonogashira and Buchwald-Hartwig couplings, to cyanation, addition reactions of arylboronic acids, and coupling reactions involving terminal alkynes. The preliminary achievements regarding their applications to homogeneous catalysis are concisely described herein.Cyclopalladated ferrocenylimines as a novel kind of highly efficient palladium catalyst precursors, which are air-stable and easy to handle, have been successfully applied in a wide variety of catalytic reactions ranging from classical reactions, such as Heck, Suzuki, Sonogashira and Buchwald-Hartwig couplings, to cyanation, addition reactions of arylboronic acids, and coupling reac- tions involving terminal alkynes. The preliminary achievements regarding their applications to homogeneous catalysis are con- cisely described herein.

关 键 词：二茂铁亚胺 催化剂前体 均相催化 催化效率 钯 催化反应 芳基硼酸 加成反应 

分 类 号：O643.36[理学—物理化学] TN241[理学—化学]