松香基环氧树脂的合成及性能研究  

Study on Synthesis and Properties of Epoxy Resin Based on Rosin

作　　者：刘海峰[1,2] 沈敏敏[2] 张卡[1,2] 哈成勇[2] 

机构地区：[1]中国科学院研究生院,北京100039 [2]中国科学院广州化学研究所,广东广州510650

出　　处：《精细化工》2010年第9期922-925,共4页Fine Chemicals

基　　金：广东省粤港关键领域重点突破项目(2006A25002002)~~

摘　　要：通过丙烯酸松香(AR)分别与1,4-丁二醇二缩水甘油醚(BDGE)、1,6-己二醇二缩水甘油醚(HDGE)酯化反应合成出松香基环氧树脂预聚体ARBDGE和ARHDGE,丙烯酸松香分别与二乙烯三胺(DETA)、四乙烯五胺(TEPA)酰胺化反应合成出松香基聚酰胺固化剂ARDETA和ARTEPA,测试了理论配比下反应生成固化物的玻璃化转变温度(Tg)及性能;结果表明,松香基固化物硬度中等、划格实验≤3级、T-弯均为0级、耐冲击性能≥5.88 J,耐化学腐蚀合格,紫外加速老化30 d无任何变化。Epoxy prepolymers were prepared via the esterification reaction between acrylic acid rosin and 1,4-butanediol diglycidylether/1,6-hexanediol diglycidylether.Polyamide hardeners were synthesized via the amidation reaction between acrylic acid rosin and diethylenetriamine/tetraethylenepentamine.Then a new series of polymers were obtained through the reaction between prepolymers and polyamide hardeners stoichiometrically.The tests showed that the new polymers had a moderate degree of hardness;cross cut test,less than 3;T-bend,0;impact resistance,more than 5.88 J;chemical resistance,passed;and aging under ultraviolet lights for 30 d,intact.

关 键 词：丙烯酸松香 环氧树脂 耐紫外线 建筑用化学品 

分 类 号：TQ322[化学工程—合成树脂塑料工业]