SBA-15分子筛表面茂锆化合物的合成与催化硅腈化反应  

The synthesis,characterization and catalysis performance of zirconocene compounds supported on SBA-15 molecular sieve

作　　者：毛娜[1] 高子伟[1] 薛玫[1] 吴亚丽[1] 高玲香[1] 

机构地区：[1]应用表面与胶体化学教育部重点实验室,陕西师范大学化学与材料科学学院,陕西西安710062

出　　处：《陕西师范大学学报（自然科学版）》2010年第5期56-60,共5页Journal of Shaanxi Normal University：Natural Science Edition

基　　金：国家自然科学基金资助项目(20771071);新世纪优秀人才支持计划资助项目(NCET-07-0528);陕西省自然科学基金资助项目(2007B06)

摘　　要：通过两种方法合成了SBA-15分子筛表面茂锆化合物,分别对其进行了红外、元素分析、原子发射光谱、N2吸附-脱附等结构表征.将这两种化合物分别运用于催化硅腈化反应,发现室温下经超声接枝的化合物具有较高的催化转化率.实验表明:超声接枝法具有反应条件温和、操作方便及费时少等优点.The SBA-15 supported zirconocene compounds were synthesized by two methods,and characterized by FT-IR,ICP-AES,element analysis and nitrogen adsorption-desorption,respectively.Utilizing the two compounds as catalysts,respectively,the cyanosiylated reaction of benzaldehyde with trimethylsily cyanide（TMCN） was evaluated.The results showed that the higher catalytic conversion could be obtained in presence of zirconocence compounds grafted on SBA-15 under the ultrasonic radiation at room temperature.It was also found that the ultrasonic synthetic method had some advantages,such as mild reaction conditions,convenient operation and saving time.

关 键 词：表面金属有机化学 SBA-15分子筛 茂锆化合物 硅腈化反应 

分 类 号：O627.4[理学—有机化学] O643.3[理学—化学]