过渡金属配合物的合成、表征及纳米胶束自组装  

Self-assemly of Nano-micelle of Coordination Compound of Transiton Metal

作　　者：孙萃玉[1] 

机构地区：[1]威海职业学院生物与化学工程系,山东威海264210

出　　处：《广州化学》2010年第3期16-20,56,共6页Guangzhou Chemistry

摘　　要：以异烟酸和溴代十二烷为原料合成液晶基元异烟酸十二烷基酯,以水杨醛和邻氨基苯酚为原料来制各希夫碱,将希夫碱与异烟酸酯同时与过渡金属配位,透射电镜形态观测到10～60m左右的线状形态的纳米胶束。并利用红外光谱,紫外可见吸收光谱等手段对其结构和性质进行了表征。In the first, pyridine-4-carboxylic acid reacted with dodecyl bromide to give liquid crystal unit dodecyl pyridine-4-carboxylate, which was further treated with transition metal ion to form the coordination compound. The nano-micelle which was 10-60 nm of column morphology observed by TEM was formed. The structure and properties of the complex were characterized by Fourier transform infrared spectroscopy （FTIR） and ultraviolet spectrum （UV）.

关 键 词：异烟酸十二烷基酯 液晶基元:过渡金属 自组装 纳米胶束 

分 类 号：O641.4[理学—物理化学]