酚醛树脂基中孔炭块体电极的制备与电容性能  

Preparation and electrochemical properties of mesoporous carbon monoliths derived from phenolic resin

作　　者：尹金山[1] 徐斌[2] 陈晓红[1] 文越华[2] 曹高萍[2] 宋怀河[1] 

机构地区：[1]北京化工大学化工资源有效利用国家重点实验室,北京100029 [2]防化研究院,北京100083

出　　处：《北京化工大学学报（自然科学版）》2010年第5期40-43,共4页Journal of Beijing University of Chemical Technology(Natural Science Edition)

基　　金：国家"863"计划(2006AA03Z342);国家自然科学基金(20633040)

摘　　要：提出了一种有机体系超级电容器用中孔炭电极的直接成型制备方法。以热塑性酚醛树脂为前驱体,加入六次甲基四胺固化、粉压成型后进行CO2活化,制备了中孔发达的炭电极。该电极比表面积1563 m2/g,孔容1.87cm3/g,其中孔孔容占75.9%,在有机电解液1mol/L Et4NBF4/PC中具有良好的电化学性能,比电容达108 F/g,大电流倍率性能良好。A mesoporous carbon monolith for use in supercapacitors has been prepared from a thermoplastic phenolic resin by curing,molding and activation with CO2.The BET surface area of the as-prepared carbon monolith is 1563m2/g,and the total pore volume is 1.87cm3/g,of which 75.9% is mesoporous in character.The unique microstructure of the carbon monolith enables it to show good electrochemical performance in 1mol/L Et4NBF4/propylene carbonate electrolyte.It shows a capacitance of 108F/g with good rate capability.

关 键 词：炭电极 中孔 电容 

分 类 号：TQ127.1[化学工程—无机化工]