新型含BPP34C10冠醚双吡啶双齿配体的合成  

Synthesis of novel dipyridine ambidentate incorporating BPP34C10 crown ether.

作　　者：叶余原[1] 金正能[1] 郭海昌[1] 周其忠[1] 蒋华江[1] 

机构地区：[1]台州学院化学系,浙江临海317000

出　　处：《浙江大学学报（理学版）》2010年第5期563-567,共5页Journal of Zhejiang University（Science Edition）

基　　金：国家自然科学基金资助项目(20172069);科技部基金资助项目(G2000078101);浙江省自然科学基金资助项目(Y406341)

摘　　要：以Sonogashira偶联反应为关键反应来合成化合物4.设计并且用Suzuki偶联反应为关键反应,合成了新型含BPP34C10冠醚的180°双吡啶双齿配体.该双吡啶双齿配体有两个配位点,有望和铂受体用于自组装成新型的超分子建筑.Sonogashira coupling reaction was used as a key step to synthesize compound 4.It is synthesized that a novel BPP34C10 crown ether based 180° dipryidine ambidentate donor by designing and using Suzuki coupling reaction as a key step.This dipyridine ambidentate ligand had 2 coordinating points,which could be used in self-assembly with Pt acceptor into novel supramolecular structure in future.

关 键 词：冠醚 双吡啶 双齿配体 

分 类 号：O62[理学—有机化学]