稀土催化降冰片烯与甲基丙烯酸特丁酯共聚研究  

Copolymerization of Norbornene and Tert-butyl Methacrylate Catalyzed by Nd(naph)_3-Al(i-Bu)_3

作　　者：陈斌[1] 邵丹凤[1] 胡敏杰[1] 杨建平[1] 房江华[1] 高浩其[1] 

机构地区：[1]宁波工程学院化工系,浙江宁波315016

出　　处：《宁波大学学报（理工版）》2010年第4期98-100,共3页Journal of Ningbo University：Natural Science and Engineering Edition

基　　金：浙江省自然科学基金(Y406370);宁波市自然科学基金(2009A610044);宁波市人才培养基地项目(JD08012)

摘　　要：研究了Nd(naph)3-Al(i-Bu)3(naph=环烷酸)催化降冰片烯(NB)与甲基丙烯酸特丁酯(TBMA)共聚反应条件、催化剂用量及钕铝比影响.并用核磁共振、红外光谱法研究了共聚物的组成.结果表明:稀土催化剂在温和的反应条件下有较好的催化性能.The characteristics of copolymerization of norbornene and tert-butyl methacrylate by Nd（naph）3-Al（i-Bu）3,as well as the structure of the copolymer,are studied.The polymerization reactions are activated under nitrogen atmosphere using syringe technique.The copolymer is characterized by IR and NMR.The copolymerization can be implemented in the solvents such as aromatic hydrocarbon.The suitable Al/Nd molar ratio is found to be 30～90;the molecular weight distribution is Mw/Mn=1.57～1.79;and the molecular weight of copolymer varies with the change of monomer molar ratio.

关 键 词：环烷酸钕 三异丁基铝 降冰片烯 丙烯酸特丁酯 共聚 

分 类 号：O631.5[理学—高分子化学]