快速凝固Ni50Al50合金加氢催化剂的研究  

Study on Hydrogenation Catalysts Made by Ni50Al50 Rapidly Solidified Alloys

作　　者：陈向明[1] 张国胜[1] 王西科[1] 沈宁福[1] 

机构地区：[1]郑州工业大学材料科学与工程系

出　　处：《郑州工业大学学报》1999年第2期57-60,共4页Journal of Zhengzhou University of Technology

基　　金：化工部重点基础研究资助

摘　　要：以旋铸法制备快速凝固Ｎｉ５０Ａｌ５０合金条带，经球磨、活化处理后制成了骨架镍催化剂．利用金相检验，ＸＲＤ，ＢＥＴ等技术对催化剂的整体结构和表面状态进行分析，发现快凝催化剂与常规催化剂相比，具有较小的比表面积，相似的晶粒度和略大的点阵参数．对比研究了常规骨架镍催化剂和快凝骨架镍催化剂的油脂加氢性能，结果表明，在相同的化学反应条件下，快凝骨架镍的油脂加氢活性比常规催化剂的高出约０．５倍．Rapidly solidified Ni50Al50 alloy ribbons are prepared, ground and activated into RaneyNi catalyst, then they are investigated and analyzed with X-ray diffraction (XRD), BET measurements,The results indicate that the rapidly solidified Ni50Al50 catalyst has smaller surface area, similar grain size and a little bigger lattice parameter, compared with conventionally prepared Ni50Al50 catalyst.The results of the oil hydrogenation show that the activity of rapidly solidified Ni50Al50 catalyst is about half times higher than that of the conventionally prepared Ni50Al50 catalyst under the same reaction conditions.

关 键 词：快速凝固 骨架镍催化剂 镍铝合金 加氢 催化剂 

分 类 号：TQ426.82[化学工程] O643.36[理学—物理化学]