水杨醛缩邻甲苯胺Schiff碱及其Zn(Ⅱ)配合物的合成与表征  

Synthesis and characterization of Zn(Ⅱ) complex derived from salicylaldehycle and o-toluidine

作　　者：李轶[1] 

机构地区：[1]陕西省石油化工研究设计院,陕西西安710054

出　　处：《应用化工》2010年第9期1370-1372,1375,共4页Applied Chemical Industry

摘　　要：由水杨醛和邻甲苯胺缩合形成的不对称Sch iff碱与Zn(Ⅱ)盐反应得到了金属配合物。通过元素分析、红外光谱、紫外-可见光谱、核磁共振氢谱(1H NMR)及13C谱(13C NMR)等分析测试手段对配体及其配合物进行了结构表征,确定了配合物的可能结构,结果表明,配体通过N,O原子与金属离子配位。A Schiff base derived from salicylaldehycle and o-toluidine and its complex of Zn（Ⅱ） were synthesized.The ligand and its complexe were characterized by IR spectra,UV-visible spectra,1H NMR,13C NMR and TG-DTA analysis.The possible structure of the complexs was proposed and it is possible to conclude that the ligand is attached to the metal ion by oxygen and nitrogen atoms.

关 键 词：SCHIFF碱 配合物 合成与表征 

分 类 号：O69[理学—化学]