1-(4-安替比林)-3-(对苯磺酸)三氮烯的合成及其与汞Ⅱ的显色反应  

Synthesis of 1-(4-antipyrine)-3-(sulfanilic acid)-triazene and its color reaction with mercury Ⅱ

作　　者：陈文宾[1,2] 胡庆昊[2] 王琼[2] 郑秋霞[2] 马卫兴[2] 许兴友[2] 

机构地区：[1]淮海工学院江苏省海洋资源开发研究院,江苏连云港222005 [2]淮海工学院化学工程学院,江苏连云港222005

出　　处：《冶金分析》2010年第9期32-36,共5页Metallurgical Analysis

基　　金：教育部重点实验室开放基金资助项目(CPEUKF06-04);江苏省自然科学基金企业博士项目(BK2009652);淮海工学院江苏海洋资源开发研究院基金资助项目

摘　　要：合成并鉴定了一种新的三氮烯试剂1-(4-安替比林)-3-(对苯磺酸)三氮烯(ASTA),研究了该试剂与HgⅡ的显色反应条件,建立了一个测定汞(的光度分析新方法。实验结果表明,在Tween-80溶液存在下,在硼砂-氢氧化钠介质中,ASTA与汞(发生灵敏的显色反应,生成络合比为2∶1的橙红色络合物。络合物的最大吸收峰位于488 nm,表观摩尔吸收系数为1.7×105L.mol-1.cm-1,在10 mL显色溶液中,汞(量在0.5～15μg之间符合比尔定律,检出限为0.16 mg/L。该显色反应用于铅锌矿样品中汞(的测定,测定结果与原子吸收光谱法相一致,加标回收率约为104%,相对标准偏差(n=6)≤4.4%。The synthesis of a new triazene reagent 1-（4-antipyrine）-3-（sulfanilic acid）-triazene（ASTA） and its color reaction with HgⅡ was studied and a new spectrophotometric method for the determination of Hg was established.The results showed that in the presence of micromulsion Tween-80,ASTA could react with HgⅡ to form a red stable complex with molar ratio of 2∶1 in Na2B4O7-NaOH medium.The maximum absorption peak of the complex was located at 488 nm with the apparent molar absorptivity of 1.7 ×105 L·mol-1·cm-1.Beer′s law was obeyed in the range of 0.5-15 μg/10 mL for HgⅡ and detection limit was 0.16 mg/L.This method has been applied to the determination of HgⅡ in lead-zinc ore samples,and the results were in accordance with those obtained by AAS method with recoveries about 104 % and RSD（n=6） not more than 4.4 %.

关 键 词：1-(4-安替比林)-3-(对苯磺酸)三氮烯 分光光度法 巯基葡聚糖凝胶 汞Ⅱ 

分 类 号：X832[环境科学与工程—环境工程]