新型杯芳烃衍生物的合成及结构表征  

Synthesis and Characterization of Novel Calixarene Derivatives

作　　者：马丽[1] 金毅[2] 王文艳[1] 王立娟[1] 张丽洋[1] 丁伟[3] 

机构地区：[1]大庆化工研究中心 [2]大庆石化公司环保监测站 [3]大庆石油学院,大庆163714

出　　处：《精细石油化工进展》2010年第9期32-36,共5页Advances in Fine Petrochemicals

基　　金：中国石油天然气集团公司石油科技中青年创新基金项目(06E1008)

摘　　要：以对叔丁基苯酚、甲醛、氢氧化钠、苯酚、浓硫酸、碳酸钠、正溴代烷烃等为原料,经缩聚反应、脱烷基化反应、磺化反应、醚化反应合成了一系列水溶性杯[4]芳烃低聚磺酸钠产品。利用红外光谱、核磁共振氢谱对中间体及产物进行了结构表征;证实了合成中间体和目标产物符合设计的分子结构。用滴体积法测定一系列表面活性剂水溶液25℃时的表面张力,结果表明,1-C_4,1-C_6,1-C_8和1-C_(10)表面活性剂分别能将水的表面张力降至32.06,34.96,42.35和45.35mN/m,临界胶束浓度分别为1.26×10^(-3),0.32×10^(-3),1.78×10^(-3)和1.2×10^(-3)moL/L。对所合成的表面活性剂进行界面张力扫描法测定,结果表明,当1-C_4,1-C_6,1-C_8和1-C_(10)表面活性剂的烷烃碳数分别为8,6,8,6时,表面活性剂的界面张力均达最小值。A series of water - soluble calyx [ 4 ] arene alkyl - ether sulfonates were synthesized from p - tertbutylphenol, formaldehyde, phenol, sulfuric acid, and bromaoalkane by five - step process involving polycondesation, antialkylation, sulfonation and etherification. The intermediate and final product were characterized by IR and 1 H NMR. The intermediate and final product were confirmed to be the designed molecular structure. The surface tensions of a series of surfactant solutions were measured by drop - volume method at 25 ℃ and the result showed that 1 - C4,1 - C6,1 - C8, and 1 - C10 surfactants could decrease the surface tension of water to 32.06, 34.96, 42.35 and 45.35 mN/m respectively. The CMC values were 1.26×10^-3,0.32 ×10^-3, 1.78×10^-3 and 1.2×10^-3 mol/L. The interface tensions of the surfactants were the minium for 1 - C4, 1 -C6, 1 -C8, and 1 -C10 with carbon number in alkyl group in the surfactants.

关 键 词：杯芳烃 表面张力 界面张力 

分 类 号：TQ241[化学工程—有机化工]