Zn/AlCl_3对高烯丙基醇无溶剂合成的影响  

The Solvent-free Synthesis of Homoallyl Alcohols by Promotion of Zn/AlCl_3

作　　者：严文君[1] 甘贤雪[1] 王丽[1] 李娜[1] 

机构地区：[1]宜宾学院化学化工学院,四川宜宾644007

出　　处：《内江师范学院学报》2010年第10期46-48,共3页Journal of Neijiang Normal University

基　　金：宜宾学院院级青年基金项目(2008QJ33;2008QJ30)

摘　　要：在室温无溶剂条件下,Zn/AlCl3能够促进芳香醛和烯丙基溴发生烯丙基化反应合成高烯丙基醇,该方法具有环境友好、操作简便、产率高等特点.产物的结构经IR和1H NMR确证.Under solvent-free conditions,it was found that Zn/AlCl3 could efficiently mediate the carbonyl allylation reaction of aldehyde and allyl bromide to give the corresponding homoallylic alcohols at room temperature.The merits of this protocol are environmentally benign,and characterized by simple operation,convenient work-up and good yields.The structures of the products were confirmed by IR and 1H NMR.

关 键 词：Zn/AlCl3 高烯丙基醇 醛 无溶剂 

分 类 号：O622.3[理学—有机化学]