改性BMI/苯并噁嗪树脂固化反应特性研究  

Study on characteristic of curing reaction for modified BMI/benzoxazine resin

作　　者：李玲[1] 陈剑楠[1] 

机构地区：[1]中北大学材料科学与工程学院,山西太原030051

出　　处：《中国胶粘剂》2010年第10期6-10,共5页China Adhesives

基　　金：山西省自然科学基金项目(20051014)

摘　　要：以双马来酰亚胺（BMI）作为苯并噁嗪（BZ）树脂的改性剂,采用非等温差示扫描量热（DSC）法及Freeman-Carroll法研究了改性BMI/BZ树脂体系的反应特性和固化反应动力学过程。结果表明：改性BMI/BZ树脂体系的凝胶时间随BMI用量增加而缩短;改性BMI/BZ树脂体系的固化反应只有一个放热峰,其峰顶温度（230℃左右）明显低于纯BZ体系,并且与BMI用量无关;改性BMI/BZ树脂体系的固化反应近似于1级反应,当w（BMI）=30%~50%时,所建立的固化反应动力学模型在10℃/min时能较好描述改性树脂体系的固化反应过程。With bismaleimide（BMI） as modifier of benzoxazine（BZ） resin,so the characteristics and kinetics process of curing reaction were investigated by non-isothermal DSC（differential scanning calorimetry） and Freeman-Carroll method for modified BMI/BZ resin system.The results showed that the gelation time of modified BMI/BZ resin system was shortened with increasing BMI content.The curing reaction of modified BMI/BZ resin system had only one exothermic peak,the peak temperature（about 230 ℃） of modified BMI/BZ resin system was obviously lower than that of pure BZ system,and its peak temperature wasn’t related to the BMI contents.The curing reaction order of modified BMI/BZ resin system was near 1.The curing reaction kinetics models could better describe curing reaction process of modified resin systems when the mass fraction of BMI was 30%-50% and heating speed was 10 ℃/min.

关 键 词：苯并噁嗪 双马来酰亚胺 固化反应 凝胶时间 动力学 

分 类 号：TQ322.4[化学工程—合成树脂塑料工业]