一维链状配位聚合物{[Ni(4-abaH)(2,2′-bipy)(NO_3)(H_2O)](NO_3)}_n的合成与晶体结构(英文)  

Synthesis and Crystal Structure of One-Dimensional Coordination Polymer:{[Ni(4-abaH)(2,2'-bipy)(NO_3)(H_2O)](NO_3)}_n

作　　者：黄妙龄 

机构地区：[1]泉州师范学化学与生命科学学院,泉州362000

出　　处：《无机化学学报》2010年第10期1912-1915,共4页Chinese Journal of Inorganic Chemistry

基　　金：福建省科技厅项目(No.2008F5053);泉州师范学院硕士点建设立项资助

摘　　要：0 Introduction The design and synthesis of coordination polymershas been a subject of intense research due to their novel structures such as diamond,square network,brick wall network,octahedral network and soThe title compound,{[Ni（4-abaH）（2,2＇-bipy）（NO3）（H2O）]（NO3）}n,where 4-abaH=4-aminobenzoic acid and 2,2＇-bipy =2,2＇-bipyridine,was synthesized and its crystal structure was determined by X-ray diffraction analysis.The crystal is of monoclinic,space group P21/c with a=1.435 45（13） nm,b=0.850 15（8） nm,c=1.643 08（15） nm,β=93.570 0（10） °,V=2.001 2（3） nm3,Z=4,Mr=494.07,Dc=1.640 g·cm-3,μ=1.033 mm-1,F（000）=1 016,R1= 0.024 9,wR2=0.058 6.The Ni atoms are octahedrally coordinated by three N atoms from 2,2＇-bipyridine and 4abaH ligand,and three O atoms from nitrate,4-abaH ligand and water molecule,respectively.The complex shows a one-dimensional zigzag chain bridged by 4-abaH molecules.CCDC：692857.

关 键 词：镍配合物 2 2′-联吡啶 4-氨基苯甲酸 配位聚合物 晶体结构 

分 类 号：O614.813[理学—无机化学]