模拟酶催化剂催化氧气液相氧化对硝基甲苯邻磺酸的研究 Ⅰ.催化剂对反应的影响  

Oxygen Oxidation of p Nitrotoluene o sulfonic Acid with \= Simulated Enzyme Catalyst\= Effect of Catalyst on Reaction

作　　者：高文涛[1] 张淑芬[1] 杨锦宗[1] 黄霖[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室

出　　处：《精细化工》1999年第3期32-35,共4页Fine Chemicals

基　　金：国家自然科学基金

摘　　要：研究了催化剂种类及用量对氧气液相氧化对硝基甲苯邻磺酸（ＮＴＳ）制取４，４’二硝基二苯乙烯２，２’二磺酸（ＤＮＳ）的影响。发现在水介质中以价廉易得的模拟酶催化剂，在其最佳用量ｗ（底物）＝１％、ｃ（ＮａＯＨ）＝１．０ｍｏｌ／Ｌ、ｃ（ＮＴＳ）＝０．３８ｍｏｌ／Ｌ时，６０℃下反应１８ｈ，可以获得８１．８％的粗品收率，其纯度可达９６．７％。ＤＮＳ的结构通过核磁共振谱得以确认。The effect of catalyst and its consumption on preparation of 4,4'dinitrostilbene2,2'disulfonic acid by means of oxygen oxidation of p nitrotoluene o sulfonic acid in liquidphase were investigated.The results showed that oxygen liquidphase oxidation of p nitrotoluene o sulfonic acid by choosing simulated enzyme as catalysts with 1% NTS( m/m ), c (NaOH)=1mol/L, and c (NTS)=0.38mol/L in water solution at 60 for 18h could give 4,4'dinitrostilbene2,2'disulfonic acid in 81.8% yield and in 96.7% purity which was determined with HPLC.The structure of DNS was confirmed by \+1 HNMR.\=

关 键 词：对硝基甲苯邻磺酸 氧气 催化氧化 模拟酶催化剂 

分 类 号：TQ426.97[化学工程] TQ247.51