CO_2开关型溶剂、溶质及表面活性剂  

CO_2 Switchable Solvents,Solutes and Surfactants: State of the Art

作　　者：王九霞[1,2] 苏鑫[1,2] P.G.Jessop 冯玉军[1] 

机构地区：[1]中国科学院成都有机化学研究所,成都610041 [2]中国科学院研究生院,北京100049 [3]Department of Chemistry,Queen's University

出　　处：《化学进展》2010年第11期2099-2105,共7页Progress in Chemistry

基　　金：四川省杰出青年基金项目(No.2010JQ0029)资助

摘　　要：CO2诱导的开关型溶剂、溶质及表面活性剂是指在通入和排出CO2后,其溶液性质能发生可逆变化的新型溶剂、溶质及表面活性剂,是典型的环境刺激响应型智能化合物。本文综述了CO2诱导的开关型溶剂、溶质和表面活性剂的结构、性能及研究进展,并指出了这些开关型溶剂、溶质和表面活性剂的发展方向及应用前景等。CO2-induced switchable solvents,solutes and surfactants represent a novel family of smart compounds appeared recently.When bubbling and removing CO2,the properties of these compounds can be reversibly switched.The progress on CO2 switchable solvents,solutes and surfactants was reviewed in this article,including their structures,properties and future development.The existing problems,the development prospect and potential applications of such switchable compounds were outlooked.

关 键 词：开关型溶剂 开关型溶质 开关型表面活性剂 CO2开关 环境刺激响应 离子液体 

分 类 号：O647.2[理学—物理化学] TQ423[理学—化学]