取代四苯基卟啉的紫外、荧光光谱及电化学性质  

The UV-Vis,Fluorescence and Electrochemical Properties of Tetraphenylporphyrin and Its Derivatives

作　　者：夏梅君[1] 申琦[1] 郭九吉[1] 程玲玲[1] 石伟民[1] 冶保献[1] 

机构地区：[1]郑州大学化学系,河南郑州450001

出　　处：《郑州大学学报（理学版）》2010年第4期83-87,共5页Journal of Zhengzhou University:Natural Science Edition

基　　金：国家自然科学基金资助项目;编号20775073;20505015

摘　　要：采用紫外可见光谱法、荧光光谱法以及循环伏安法研究了取代四苯基卟啉的光谱学和电化学性质.探讨了不同取代基对其光谱及电化学性质的影响,并对实验结果进行了分析和归纳.The spectral and electrochemical behaviors of tetraphenylporphyrin and its derivatives are studied by UV-Vis spectrum, fluorescence spectrum and cyclic voltammetry method. The effects of various substituent groups on spectroscopy and electrochemistry properties are discussed and explained by using structural parameters and theory analysis.

关 键 词：四苯基卟啉 取代基 紫外 荧光 电化学 

分 类 号：O657.3[理学—分析化学] O657.1[理学—化学]