Synthesis and modification of well-ordered layered cathode oxide LiNi_(2/3)Mn_(1/3)O_2  

作　　者：XIONG XiaoQin JIANG Yan XIA ShengAn ZHANG WuXing Yuan LiXia LIU ShanTang HUANG YunHui 

机构地区：[1]School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong Univer- sity of Science and Technology, Wuhan 430074, China [2]School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430073, China

出　　处：《Chinese Science Bulletin》2010年第30期3419-3423,共5页

基　　金：supported by the National Natural Science Foundation of Distinguished Young Scientists of China (50825203);the National HighTech Research & Development Program of China (2009AA03Z225);the Natural Science Foundation of Hubei Province of China (2008CD-A026)

摘　　要：Oxalic-acid-based co-precipitation method was employed to prepare LiNi2/3Mn1/3O2 sample with a high-ordered structure. Li+,Ni2+ and Mn2+ acetates were used as starting materials. The influence of the amount of lithium source in the starting materials on Li+ content,disorder of Li+-Ni2+ ions,and electrochemical performance has been investigated. Rietveld refinement shows that the sample prepared with 20% excess Li-source in the starting materials exhibits a perfect ordered structure. A specific discharge capacity is as high as 172 mAh/g at C/20 in the voltage range of 4.35?2.7 V. However,the cyclability is not satisfactory:about 25.3% fade in capacity was observed over 50 cycles. Chemically stable SiO2 was coated on the surface of LiNi2/3Mn1/3O2 particles. A significant improvement in cyclability was attained with 3 wt% SiO2 coating,which is ascribable to the protection of LiNi2/3Mn1/3O2 particles from being dissolved into the electrolyte.Oxalic-acid-based co-precipitation method was employed to prepare LiNi2/3Mn1/3O2 sample with a high-ordered structure. Li＋, Ni2＋ and Mn2＋ acetates were used as starting materials. The influence of the amount of lithium source in the starting materials on Li~ content, disorder of Li^-Ni2＋ ions, and electrochemical performance has been investigated. Rietveld refinement shows that the sample prepared with 20% excess Li-source in the starting materials exhibits a perfect ordered structure. A specific discharge capacity is as high as 172 mAh/g at C/20 in the voltage range of 4.35-2.7 V. However, the cyclability is not satisfactory： about 25.3% fade in capacity was observed over 50 cycles. Chemically stable SiO2 was coated on the surface of LiNi2/aMn1/3O2 particles A significant improvement in cyclability was attained with 3 wt% SiO2 coating, which is ascribable to the protection of LiNi2＋3Mn1/3O2 particles from being dissolved into the electrolyte.

关 键 词：二氧化硅涂层 有序结构 Rietveld拟合 正极 层状 修改 合成 起始原料 

分 类 号：TQ174.758[化学工程—陶瓷工业] TG174.4[化学工程—硅酸盐工业]