Preparation of chemical manganese dioxide from manganese sulfate  

作　　者：FU Jiangang, HE Zhangxing, WANG Hui, LIANG Wei, GUO Chao College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China 

出　　处：《Mining Science and Technology》2010年第6期877-881,共5页矿业科学技术（英文版）

基　　金：National Natural Science Foundation of China (No50704036);the Natural Science Foundation of Hunan Province (No08JJ3027) for their financial support

摘　　要：Chemical Manganese Dioxide （CMD） was prepared by an alkali-oxidation method. There are several virtues to this environmental friendly and clean process, including the nontoxic and harmless reagents and products, easy operations, no pollutants, easily obtained raw materials and moderate reaction conditions. The synthesized manganese dioxide was characterized by XRD and SEM. The particles were small, consisting primarily of α-MnO2 and γ-MnO2. Experimental results showed that the optimum conditions were： MnSOa.H20 to NaOH ratio, 1.0：2.4; catalyst concentration （catalyst TF-2）, 6% of the MnSO4; initial solution pH, 11; reaction time and temperature, 20 min and 80 ℃; air flow, 0.20 m3/h; and, agitation rate, 700 r/rain. The conversion of MnSO4 can exceed 80% under these optimum conditions.Chemical Manganese Dioxide (CMD) was prepared by an alkali-oxidation method. There are several virtues to this environmental friendly and clean process, including the nontoxic and harmless reagents and products, easy operations, no pollutants, easily obtained raw materials and moderate reaction conditions. The synthesized manganese dioxide was characterized by XRD and SEM. The particles were small, consisting primarily of α-MnO2 and γ-MnO2. Experimental results showed that the optimum conditions were: MnSO4?H2O to NaOH ratio, 1.0:2.4; catalyst concentration (catalyst TF-2), 6% of the MnSO4; initial solution pH, 11; reaction time and temperature, 20 min and 80 °C; air flow, 0.20 m3/h; and, agitation rate, 700 r/min. The conversion of MnSO4 can exceed 80% under these optimum conditions.

关 键 词：MNSO4 alkali-oxidation chemical manganese dioxide clean process 

分 类 号：TQ137.12[化学工程—无机化工] TQ233.1