Synthesis and Characterization of Oxy-Vanadium （Ⅳ） Complex of 4-（2, 4-dihydroxybenzaldimine） Antipyrine  

作　　者：Ramadan M. El-mehdawi Abdussallam N. Eldewik Khaled M. Kreddan Fathhia A. Treish Mufida M. BenYounes Abtisam A. Aboushagour Zinab A. Elkamoshi 

机构地区：[1]Chemistry Department, Faculty of Science, Al-Fateh University, Tripoli, Libya [2]Chemistry Department, Faculty of Science, University of Aljabal Algharbi, Zawia, Libya [3]Libyan Petroleum Institute, Tripoli, Libya

出　　处：《Journal of Chemistry and Chemical Engineering》2010年第11期49-53,共5页化学与化工（英文版）

摘　　要：The reaction of VCl3 with 4-（2, 4-dihydroxybenzaldimine） antipyrine （LH） in a l ： 1 molar ratio results in formation of the general complex of [VOL（CI）OH]. The nature of bonding and stereochemistry of the complex was deduced from the elemental analysis, IR, UV-Vis, 1H and ^13C NMR spectroscopy. This complex has a coordination number five （square pyramidal） as known for many vanadyl complexes. The formation of the vanadyl ion （VO^2＋） and the mode of bonding of the Schiff base through the oxygen of the pyrazol ring and the nitrogen of the azomethine group to the vanadyl ion were established by IR technique.

关 键 词：Schiff base Oxy-Vanadium（IV） complex ^1H and ^13C NMR. 

分 类 号：O614.511[理学—无机化学] Q513[理学—化学]