乙烯基单体/N-取代马来酰亚胺共聚合动力学  

Kinetics of Vinyl Monomer/NSubstituted Maleimide Copolymerization

作　　者：单国荣[1] 翁志学[1] 黄志明[1] 潘祖仁[1] 

机构地区：[1]浙江大学化工系

出　　处：《高等学校化学学报》1999年第4期651-655,共5页Chemical Journal of Chinese Universities

基　　金：教育部博士学科点专项科研基金

摘　　要：详细研究了聚合温度、引发剂用量、单体配比对苯乙烯（Ｓｔ）／Ｎ－苯基马来酰亚胺（ＰＭＩ）共聚合动力学的影响．对Ｓｔ、甲基丙烯酸甲酯（ＭＭＡ）和丙烯腈（ＡＮ）等单一或混合单体与ＰＭＩ、Ｎ－环己基马来酰亚胺（ＣｈＭＩ）和Ｎ－邻氯苯基马来酰亚胺（ｏ－ＣＰＭＩ）的共聚合进行了研究。The effects of reaction temperature, initiator concentration, and molar fraction of monomer on the copolymerization kinetics of styrene/Nphenylmaleimide were studied in detail. The copolymerizations of styrene, methyl methacrylate, acrylonitrile, or their mixtures with \{Nphenylmaleimide\}, Ncyclohexylmaleimide, or N(ochlorophenyl)maleimide were also investigated and discussed with the structure of comonomer pairs.

关 键 词：乙烯基单体 马亚酰胺胺 共聚合动力学 共聚物 

分 类 号：O632.12[理学—高分子化学] O633.22[理学—化学]