基于L-(+)-酒石酸二乙酯的光学活性聚酯的合成与表征  

SYNTHESIS AND CHARACTERIZATION OF OPTICALLY ACTIVE POLYESTER BASED ON L (+) DIETHYL TARTRATE

作　　者：粟权[1] 陈传福[1] 陈永明[1] 习复[1] 

机构地区：[1]中国科学院中国石化总公司高化联合开放实验室中国科学院化学研究所

出　　处：《高分子学报》1999年第2期217-220,共4页Acta Polymerica Sinica

基　　金：国家自然科学基金

摘　　要：对基于Ｌ（＋）酒石酸二乙酯和邻、间、对位苯二甲酰氯的光学活性聚酯进行了合成．这类聚酯的比旋光度与所采用的二酰氯有关，依次为对苯＞间苯＞邻苯．通过模型化合物、最小能量优化及圆二色谱等分析表征阐明了这类聚酯不同的结构形态特征．Optically active polyesters based on L (+) diethyl tartrate and terephthaloyl chloride (TPC),isophthaloyl chloride (IPC),o phthaloyl chloride (OPC) are synthesized and characterized by using model compound,computer simulation for the geometric minimization,UV spectra and circular dichroism.The optical activity of obtained polyesters has close relationship with the diacid chlorides used,i.e:TPC>IPC>OPC.The morphology of the polyesters have been discussed by DSC and X ray methods.

关 键 词：光学活性 聚酯 酒石酸二乙酯 合成 

分 类 号：O633.14[理学—高分子化学]