喹啉方酸菁光敏剂的合成及其日光催化气相苯  

Synthesis of Quinoline Squarylium Cyanine and Catalytic Oxidation of Benzene Using Photosensitizer in Sunlight

作　　者：马艳丽[1] 方桂珍[1] 马英梅[1] 张锐[1] 金钟玲[1] 

机构地区：[1]生物质材料科学与技术教育部重点实验室(东北林业大学),哈尔滨150040

出　　处：《东北林业大学学报》2010年第11期122-124,共3页Journal of Northeast Forestry University

基　　金：哈尔滨科技创新人才研究专项资金(2009RFQXG064);中央高校基本科研业务费专项资金(41409109);黑龙江省重点项目(GB06B501-3)

摘　　要：以四方酸与2-甲基喹啉为原料合成2,4-双(4-甲基喹啉基-3-甲基)环丁二烯-1,3-二甲醚方酸菁染料(简称DQCB),并制备了响应日光的DQCB敏化的nano-TiO2复合催化剂。利用MS、EA、H1-NMR和FT-IR确定其化学结构;以UV-VisDRS研究其光谱响应性质;并以GC为检测手段研究了DQCB敏化的nano-TiO2复合催化剂日光催化气体苯的活性。研究表明:DQCB对光子能量的吸收范围为200～800nm,且吸光能力强;日光下反应78h,DQCB-nano-TiO2复合物1对苯的降解率为97.69%,较纳米TiO2提高36.96%。2,4-bis（4-methylquinolin-3-yl） cyclobuta-1,3-diene-1,3-dimethoxy（DQCB） was synthesized with 2-methyl quinoline and squaric acid.It was used as dye to prepare DQCB sensitized nano-TiO2 catalyst which can work in sunlight.The structure of DQCB was confirmed by MS,EA,H1-NMR and FT-IR spectroscopy,and diffuse reflectance spectra was used to characterize the optical property.The benzene removal of DQCB-nano-TiO2 complex catalyst was determined by gas chromatography.Results show that the DQCB has an intense absorption in the light region of 200-800 nm.The benzene removal of DQCB-nano-TiO2 complex catalyst for 78h was 97.69%,and it was 36.96% higher than that of nano-TiO2.

关 键 词：方酸菁 光敏剂 合成 

分 类 号：X511[环境科学与工程—环境工程]