聚酰胺-胺树形分子核的微波合成  

Microwave-assisted Synthesis of Polyamidoamine Dendrimer Core

作　　者：周旭[1] 吴江渝[1] 李妍[1] 姜铁坤[1] 

机构地区：[1]武汉工程大学材料科学与工程学院,武汉430073

出　　处：《材料工程》2010年第11期26-29,共4页Journal of Materials Engineering

基　　金：武汉市青年科技晨光计划项目(200950431195);湖北省教育厅科学研究计划重点项目(D20081501)

摘　　要：采用微波辅助加热的方法从三乙醇胺出发合成聚酰胺-胺树形分子核。结合IR和1H NMR表征手段,证明合成产物与目标分子结构一致。通过单因素对比实验研究了微波功率与产率之间的关系,并综合实验数据确定出了合适的微波反应条件。微波反应30,60,50min,中间产物三腈、三酯及目标产物三胺的产率分别达到72.5%,73.8%,69.3%。Aiming to improve the synthetic efficiency of polyamidoamine dendrimer,the triethanolamine-based dendrimer core was prepared through microwave-assisted synthesis procedure.The molecule structure of each product was characterized by Infrared Spectra（IR） and Hydrogen Nuclear Magnetic Resonance（1H NMR）.The effect of the power of microwave on the product yield was investigated and the synthetic conditions were optimized for each step of reaction.After 30min,60min and 50min of microwave-assisted reaction,the yield of the product was 72.5%,73.8%,and 69.3% for trinitrile,triester,and triamine,respectively.

关 键 词：微波辅助合成 树形分子核 三乙醇胺 优化 

分 类 号：O621.3[理学—有机化学]