间苯三酚正辛醚的合成  

Synthesis of n octyl ether of phloroglucin

作　　者：孙祥玉[1] 黄玉梅[1] 赵瑶兴[1] 樊美公[2] 

机构地区：[1]中国科学技术大学研究生院 [2]中国科学院感光化学所

出　　处：《化学试剂》1999年第2期68-70,共3页Chemical Reagents

摘　　要：研究了间苯三酚在非质子极性溶剂中，以１８－冠醚－６作催化剂的Ｗｉｌｉａｍｓｏｎ反应，成功地合成了间苯三酚的单辛基、二辛基和三辛基醚，并对反应条件和产物组成关系进行了讨论。The Williamson reaction of phloroglucin in non protonic polar solvent and catalysis by 18 crown 6 was investigated.The mono ,di and tri octyl ethers of phloroglucin have been synthesized successfully.The relation between reaction conditions and composition of products were also discussed.

关 键 词：Williamson反应 间苯三酚醚 相转移催化 冠醚 

分 类 号：O625.322[理学—有机化学]