氧在直接耐晒翠蓝GL修饰电极上的催化还原  

Catalytic Reduction of Oxygen on Glassy Carbon Electrode Modified with Dyestuff Direct Light Turquoise GL

作　　者：潘湛昌[1] 曾章逸[1] 李琼[1] 

机构地区：[1]广东工业大学化工系,广州510090

出　　处：《物理化学学报》1999年第5期462-466,共5页Acta Physico-Chimica Sinica

基　　金：广东省自然科学基金

摘　　要：The behavior of catalytic reduction of oxygen on modified electrodes of three types are studied using cyclic voltanuntry in an acidic solution. The first electrode modified with industrial dyestuff Direct Light Turquoise GL(denoted as GL) has notable catalytic activity, two reduction peaks of O2 appear on CV curve (Ep is - 0. 25 V and - 0. 40 V respectively), but its stability is poor The second electrode modified with poly(4-vinyl-pyridine) and GL shows quite good catalytic performance. Both activity and stability are much better than those of the first electrode, in in the CV curve equals 200% of that of the lst electrode and the Ev for the first peak has shifted positively about 0. 05 V.The catalytic perfonnance of the third electrode modified with Nafion and GL is a little bid better than that of the first electrode, but is much worse than that of the second electrode. The reason of differences in the catalytic performances of these electrodes are discussed.The behavior of catalytic reduction of oxygen on modified electrodes of three types are studied using cyclic voltanuntry in an acidic solution. The first electrode modified with industrial dyestuff Direct Light Turquoise GL(denoted as GL) has notable catalytic activity, two reduction peaks of O2 appear on CV curve (Ep is - 0. 25 V and - 0. 40 V respectively), but its stability is poor The second electrode modified with poly(4-vinyl-pyridine) and GL shows quite good catalytic performance. Both activity and stability are much better than those of the first electrode, in in the CV curve equals 200% of that of the lst electrode and the Ev for the first peak has shifted positively about 0. 05 V.The catalytic perfonnance of the third electrode modified with Nafion and GL is a little bid better than that of the first electrode, but is much worse than that of the second electrode. The reason of differences in the catalytic performances of these electrodes are discussed.

关 键 词：氧化还原 修饰电极 电催化 直接耐晒翠蓝GL 

分 类 号：O646.54[理学—物理化学] O643.32[理学—化学]