发展二氧化碳的绿色高新精细化工产业链建设低碳生态产业园  

Green Chemical Eco-industry System for Producing a Series of Fine Chemical Products with CO_2 Insteaded of Phosgene

作　　者：田恒水[1] 李峰[1] 陆文龙[1] 何国锋[1] 丁同梅[1] 赵贺猛[1] 王旭涛[1] 魏永梅[1] 张武平[1] 朱云峰[1] 王贺玲[1] 

机构地区：[1]华东理工大学化工学院,上海200237

出　　处：《合成化学》2010年第B09期7-17,共11页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(20376024);国家863计划资助项目(2006AA030204)

摘　　要：本文开发了从烯烃生产环氧烷烃,二氧化碳合成碳酸二甲酯联产二元醇,以绿色化学原料碳酸二甲酯代替剧毒的光气,开发了碳酸甲乙(丙、丁、戊、己、辛酯)、二乙(丙、丁、戊、己、辛)酯、二苯酯、呋喃唑酮、碳酰肼、苯胺基甲酸甲酯、苄胺基甲酸甲酯、对苯二胺二甲酸甲酯、间羟苯胺基甲酸甲酯、间甲苯胺基甲酸甲酯、二胺基甲酸甲酯二苯甲烷、己二胺二甲酸甲酯、烷基胺甲酸甲酯、肼基甲酸甲酯、嘧黄隆、甲黄隆、氯黄隆、异氰酸酯、聚氨酯、聚碳酸酯等一系列绿色清洁生产新工艺,间接实现了二氧化碳替代剧毒的光气,形成了具有中国特色的二氧化碳的绿色高新精细化工产业链,可建设成为低碳生态产业园。In this paper,it is studied that how to synthesize dimethyl carbonate（DMC） with carbon dioxide as material and diols as co-productions,as well as how to product epoxy alkanes from olefins.And it is worth mentioning that DMC is a kind of environment-friendly chemical materials. Besides,DMC,instead of toxic phosgene,is used to develop a series of new clean technologies in this article,such as the production process of ethyl（propyl/butyl/pentyl/hexyl/oxtyl）-methyl/ diethyl/dipropyl/dibutyl/dipentyl/dihexyl/dioxtyl carbonates,furazolidone,hydrazine carbonate,methyl phenylamine/ benzylamine carbamates,dimethyl p-phenylenediamine dicarbamate,methyl m-hydroxyl-amine/m-toluidine carbamates,dimethyl 4,4＇-diphenyl methane/ dimethyl 1,6-hexanediamine dicarbamates,alkylamine methyl carbamate,methyl hydrazine,sulfometuron,metsulfuron-methyl,chlorimuron-ethyl etc.This new production technology which made use of carbon dioxide indirectly and replaced the toxic phosgene can promote optimization of chemical industry structure and shape a Green High-tech Fine Chemical Industry Eco-system for producing a series of fine chemical products with carbon dioxide. All the researches discussed above are significant.By the investigations,not only the industrial structure is optimized,but energy conservation also is promoted.

关 键 词：二氧化碳 碳酸二甲酯 清洁生产 绿色化工产业链 低碳生态产业园 

分 类 号：TQ116.3[化学工程—无机化工]