咪唑基手性硫醚衍生物的合成与表征  

Synthesis and characteristic of chiral thioethers containing imidazole

作　　者：毛璞[1,2] 刘秀君[2] 杨亮茹[2] 蔡雅静[2] 薛媛[2] 宋毛平[1] 

机构地区：[1]郑州大学化学系,河南郑州450001 [2]河南工业大学化学化工学院,河南郑州450001

出　　处：《化学研究与应用》2010年第12期1557-1560,共4页Chemical Research and Application

基　　金：国家自然科学基金资助项目(20902017)资助;郑州市科技攻关项目(083SGYG25121-11)资助

摘　　要：Using natural and commercially available L-Phenylalanine as starting material,three chiral thioethers containing imidazole ring were synthesized by condensation reaction,esterification,reduction,chlorination and subsequent substitution by thiols.The unreported products were characterized by IR,ESI MS and NMR.Using natural and commercially available L-Phenylalanine as starting material,three chiral thioethers containing imidazole ring were synthesized by condensation reaction,esterification,reduction,chlorination and subsequent substitution by thiols.The unreported products were characterized by IR,ESI MS and NMR.

关 键 词：L-苯丙氨酸 手性咪唑 硫醚 

分 类 号：O626.23[理学—有机化学]