聚硅烷光学材料的研究与应用  

Study and Application on Polysilanes Optical Materials

作　　者：张敏[1] 李如钢[1] 张荣军[1] 

机构地区：[1]山东省科学院新材料研究所,济南250014

出　　处：《材料导报（纳米与新材料专辑）》2010年第2期360-362,共3页

摘　　要：聚硅烷是一种主链完全由Si-Si组成的高聚物,其主链的σ键电子的非定域作用赋予了聚硅烷独特的光电性质,从而使其成为极有前途的功能性材料,引起了人们极大的兴趣,成为材料科学的研究热点之一。在前人研究的基础上,概述了聚硅烷的合成方法和光学性能及其在非线性光学材料、光致抗蚀剂和电致发光材料等方面的研究与应用。Polysilanes are polymers consisting of silicon silicon single bond. It is a kind of promising functional material which has drawn much attention for its unique optical and electric properties caused by the delocalization of electrons along the σ-conjugated silicon backbones. According to the former investigations, the progresses in synthesis methods and optical properties are summarized. And the applications of polysilanes in the field of non-linear optical materials, photoresist materials, electroluminescence materials and so on are also reported.

关 键 词：聚硅烷 合成 光学性能 

分 类 号：O634.41[理学—高分子化学]