多壁碳纳米管表面对硝基苯酚印迹复合材料的制备与吸附性能  

Preparation and Adsorption Properties of p-Nitrophenol Imprinted Materials Based on Multi-walled Carbon Nanotubes Surface

作　　者：张华斌[1] 张朝晖[1,2] 胡宇芳[1] 杨潇[1] 聂利华[2] 

机构地区：[1]吉首大学化学化工学院,吉首416000 [2]湖南大学化学生物传感与计量国家重点实验室,长沙410082

出　　处：《高等学校化学学报》2010年第11期2141-2147,共7页Chemical Journal of Chinese Universities

基　　金：湖南省自然科学基金(批准号:08JJ4004);湖南省科技计划项目(批准号:2009FJ3009);林产化工工程湖南省重点实验室开放基金(批准号:JDZ200903);吉首大学研究生科研创新基金(批准号:JGY200901)和吉首大学校级课题基金(批准号:09JDY007)资助

摘　　要：以多壁碳纳米管表面接枝的L-苯丙氨酸为结合位点,甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂,采用沉淀聚合技术,在碳纳米管表面制备了对硝基苯酚印迹复合材料.采用红外光谱和扫描电镜研究了该印迹复合材料的结构和形貌,结果表明,在碳纳米管表面接枝了一层稳定的印迹材料.采用高效液相色谱研究了该印迹材料的等温吸附性能,结果表明,该印迹材料对模板分子具有较大的吸附容量(Qmax=80.5μmol/g)和良好的选择吸附性能(选择因子达2.5).以该印迹材料作为固相萃取吸附剂,研究了它对对硝基苯酚和其它结构类似物混合溶液的动态吸附性能,结果表明,印迹复合材料对对硝基苯酚的吸附容量不受结构类似物浓度的影响,能较好地应用于对硝基苯酚的分离富集检测.Novel molecularly imprinted polymers were prepared successfully by employing multi-walled carbon nanotubes（MWNT） as the supported matrix,grafting of L-phenylalanine on the MWNT surface as the binding site,p-nitrophenol as template,methacrylic acid（MAA） as functional monomer and ethyleneglycol dimethyac-rylate（EGDMA） as cross-linker.The molecularly imprinted materials were characterized with infrared spec-troscopy（IR） and scanning electron microscopy（SEM）.The results show that a stable imprinted layer is graf-ted on the MWNT surface.The static adsorption experiments were also executed.A large adsorption capacity Qmax of 80.5 μmol/g and an excellent selectivity for the template of 2.5 were obtained.As solid-phase extrac-tion adsorbents,the imprinted material was applied to study the dynamic adsorption of p-nitrophenol from a mixture of p-nitrophenol and other structural analogues.The results show that the imprinted materials can ap-ply to the separation of p-nitrophenol from a mixture solution.

关 键 词：多壁碳纳米管 印迹 硝基苯酚 吸附 

分 类 号：O613[理学—无机化学] O657[理学—化学]