新型双槽光电化学反应器对活性艳红的降解研究  

Studies on degradation of reactive brilliant red X-3B in innovative dual compartment photoelectrochemical reactor

作　　者：李明玉[1] 曾凡银[1] 房献宝[1] 王君[1] 宋琳[1] 

机构地区：[1]暨南大学环境工程系,广东广州510630

出　　处：《生态环境学报》2010年第10期2474-2478,共5页Ecology and Environmental Sciences

基　　金：国家自然科学基金项目(20676050);广东省自然科学基金项目(8451063201001261);广东高校优秀青年创新人才培育项目(LYM08022);暨南大学自然基金项目(5122000251208028)

摘　　要：用热氧化法制备了TiO2/Ti薄膜电极,并用XRD和AFM对TiO2/Ti薄膜电极的晶形和表面形貌进行了表征。结果表明:热氧化法制备的TiO2主要为锐钛型纳米颗粒,直径在40 nm左右。设计了一种新型双槽光电化学反应器,用于废水的处理。以热氧化法制备的TiO2/Ti薄膜电极为阳极进行光电催化反应,同时以石墨电极为阴极用于产生双氧水,并与紫外光组成UV/H2O2体系。考察了双槽反应器中活性艳红X-3B在不同条件下的降解效果。降解结果表明:在新型反应器的阴阳两极槽中,活性艳红不仅在TiO2/Ti阳极槽中被降解,而且在石墨阴极槽中也得到降解;活性艳红在酸性条件下的降解效果最好;相对于单纯的电化学氧化和光催化,光电化学协同作用对X-3B的降解效果最好。A TiO2/Ti thin membrane electrode was made by thermal oxidation method.The crystal structure and surface morphology of the thermal oxidized TiO2/Ti electrode were characterized by X-ray diffraction（XRD） and Atomic Force Microscope（AFM）.The analytical results showed that n-type anatase nanoparticles with a diameter of nealy 40 nm was formed.An innovative two-compartment photoelectric oxidation reactor was successfully developed for wastewater treatment.The TiO2/Ti thin membrane electrode was applied in this reactor as the anode to conduct photoelectrocatalytic oxidation,and a graphite electrode was used as the cathode to electrogenerate hydrogen peroxide which can constitute UV/H2O2 system with UV light simultaneously.Degradation of Reactive brilliant red（X-3B） was performed under various experimental conditions.The degradation experiment results showed in the innovative two-compartment photoelectric oxidation reactor,the X-3B not only can be decolorized in TiO2/Ti anode compartment,but also in graphite cathode compartment;the X-3B degradation efficiency in the two compartments achieved the highest at acidic condition;comparing to the electrooxidation and photooxidation in both TiO2/Ti anode compartment and graphite cathode compartment,the degradation efficiency of photo-electro-chemical catalysis was the best.

关 键 词：二氧化钛 光电催化 活性艳红X-3B 双槽 

分 类 号：X791[环境科学与工程—环境工程]