基于π-π相互作用合成星型聚丙烯腈-石墨烯复合材料  

Preparation of Star-Shaped Polyacrylonitrile-Graphene Sheets Composite via π-π Interactions

作　　者：王平华[1] 王志刚[1] 刘春华[1] 唐龙祥[1] 向康[1] 

机构地区：[1]合肥工业大学化工学院高分子科学与工程系,合肥230009

出　　处：《功能高分子学报》2010年第4期391-395,共5页Journal of Functional Polymers

基　　金：国家自然科学基金资助项目(50573016)

摘　　要：首先合成含有6个羟基的三亚苯衍生物,然后通过氧化还原引发体系合成了星型聚丙烯腈聚合物(SPAN),最后在星型聚丙烯腈的N,N-二甲基甲酰胺溶液(DMF)中用水合肼还原氧化石墨得到均一稳定的溶液。分别通过红外光谱(FT-IR)、核磁共振谱(1H-NMR)、凝胶渗透色谱(GPC)、扫描电镜(SEM)等对产物进行表征。结果表明,星型聚丙烯腈成功吸附到石墨烯表面。Triphenylene derivative containing six hydroxyl groups was synthesized.Then,star-shaped polyacrylonitrile（SPAN） was obtained by the redox system of tetravalent cerium salt and hydroxyl groups.Finally,homogeneous black dispersion solution was obtained via the chemical reduction of graphite oxide in the N,N-dimethylformamide solution of star-shaped polyacrylonitrile FT-IR,^1H-NMR,GPC and SEM were used to investigate the chemical structure,morphology of polymer-coated graphene sheets.（Results） show that the star-shaped polyacrylonitrile is successfully adsorbed on graphene sheets.

关 键 词：三亚苯衍生物 石墨烯 星型聚丙烯腈 

分 类 号：O631[理学—高分子化学]