不对称催化加氢的研究进展  

The Research Progress of Asymmetric Catalytic Hydrogenation

作　　者：焦广霞[1] 王维德[1] 赵鹏[1] 

机构地区：[1]华侨大学化工学院,福建厦门361021

出　　处：《化工生产与技术》2010年第6期39-43,共5页Chemical Production and Technology

基　　金：福建省重点科研项目资助(2007Y0027)

摘　　要：叙述了不对称催化加氢的研究进展,分别对均相、多相不对称催化氢化以及均相催化剂的多相化进行了介绍,评述了均相、非均相不对称催化加氢的优缺点,提出了不对称催化加氢未来发展的方向和需要解决的问题,即一是如何得到更好的对映选择性,二是如何使催化剂具有更好的重复性。Asymmetric catalytic hydrogenation is one of the most important organic syntheses, which has developed rapidly in recentyears. The paper summarized the research progress of asymmetric catalytic hydrogenation, homogeneous and heterogeneous-phase asymmetric catalytic hydrogenation was introduced, respectively. And how to hydrogenise homogeneous catalysts was also discussed.Through the comparison of merits and demerits between homogeneous and heterogeneous-phase asymmetric catalytic hydrogenation,the development direction and problems need to be solved were proposed here.

关 键 词：手性 不对称催化 均相 非均相 加氢 

分 类 号：O643.32[理学—物理化学]